Journal
POLYMER INTERNATIONAL
Volume 58, Issue 11, Pages 1217-1225Publisher
WILEY
DOI: 10.1002/pi.2654
Keywords
hybrid materials; polymer host materials; polyoxometalate; supramolecular modification; surfactant-encapsulated polyoxometalates
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Funding
- National Basic Research Program [2007CB808003]
- National Natural Science Foundation of China [20574030, 20731160002]
- PCSIRT of the Ministry of Education of China [IRT0422, 1306009]
- University of Montpellier and Open Project of State Key Laboratory of Polymer Physics and Chemistry, CAS
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In this article we provide an overview of the fabrication and properties of polyoxometalate/polymer hybrid materials. Physical blending, electrostatic adsorption, covalent bonding and supramolecular modification are the main strategies to incorporate polyoxometalates into organic or inorganic (taking silica as an example) polymer matrices. The polyoxometalate/polymer hybrid materials obtained concurrently possess the unique optical, electrical or catalytic properties of polyoxometalates and the favorable processability and stability of polymer matrices. Polyoxometalate/polymer hybrid materials may have potential applications in optics, electronics, biology, medicine and catalysis. (C) 2009 Society of Chemical Industry
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