4.7 Article

Supramolecular polymers bearing disulfide bonds

Journal

POLYMER CHEMISTRY
Volume 5, Issue 22, Pages 6439-6443

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4py01003e

Keywords

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Funding

  1. National Basic Research Program of China [2013CB834502]
  2. NSFC [21274076]
  3. Foundation for Innovative Research Groups of the NSFC [21121004]
  4. NSFC-DFG [TRR 61]
  5. Science Foundation of China Postdoctor [2013M530597]

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This work is aimed to report a new type of multiple stimuli-responsive supramolecular polymers by combining dynamic covalent bonds with cucurbit[8]uril (CB[8])-based host-guest interaction. Supramonomer ( DSN) containing a disulfide bond can bind with CB[8] to fabricate supramolecular polymers by host-enhanced pi-pi interaction. Additionally, the dynamic nature of disulfide bonds and host-guest chemistry endow these supramolecular polymers with redox and guest competitive responsiveness, respectively.

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