Journal
POLYMER CHEMISTRY
Volume 5, Issue 2, Pages 341-345Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py01006f
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Funding
- National Natural Science Foundation [91227108, 921228203]
- Ministry of Science and Technology of China [2013CB834500]
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Simply introducing four viologen units to a tetraphenylmethane framework causes the corresponding viologen radical cation to strongly dimerize intermolecularly, with the apparent equilibrium constant being increased by at least 7600 times, which drives the tetrahedral molecule to self-assemble into a three-dimensional (3D) supramolecular architecture in water.
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