Journal
POLYMER CHEMISTRY
Volume 5, Issue 4, Pages 1258-1263Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py01142a
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Funding
- Australian Solar Institute/ARENA
- Victorian Organic Solar Cell Consortium
- Victorian State Government Department of Business Innovation (Victorian Science Agenda)
- Department of Primary Industries (Energy Technology Innovation Strategy)
- AAS-BMBF Australia-Germany Solar Photovoltaic Research Exchange Program
- German Science Foundation (Korean-German IR TG)
- European Community's Seventh Framework Programme ONE-P [212311]
- DFG Priority Program [SPP 1355, SPP 1459]
- DFG MU [334/32-1]
- ESF Project GOSPEL [09-EuroGRAPHENE-FP-001]
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A series of benzodithiophene-benzotriazole push-pull copolymers were synthesised and characterised and their performance in bulk heterojunction solar cells devices was assessed. By incorporating strong electron acceptor units, such as benzothiadiazole and pyridylthiadiazole, into the polymer backbone, significant absorption across the entire visible range (300 nm to 750 nm) was observed for the random copolymers. The importance of investigating photophysical as well as bulk material properties of the polymers was demonstrated with a correlation of properties with device performance.
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