Journal
POLYMER CHEMISTRY
Volume 4, Issue 2, Pages 229-232Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2py20830j
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Funding
- Welch Foundation for Chemical Research [C-1750]
- Shell Center for Sustainability
- Louis and Peaches Owen
- U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- U.S. Department of Energy, Office of Basic Energy Sciences [DE-AC02-98CH10886]
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A simplified approach towards the synthesis of high molecular weight (M-w > 50 kg mol(-1)) poly(3-hexylthiophene) (P3HT)-based all-conjugated block copolymers is demonstrated and applied to prepare a series of all-conjugated block copolymers. Grazing-incidence X-ray scattering measurements show that P3HT crystallization is suppressed in all-conjugated block copolymers with low(<25 wt%) P3HT content.
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