Journal
POLYMER CHEMISTRY
Volume 4, Issue 4, Pages 1126-1131Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2py20914d
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Funding
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1014]
- Program of Scholarship Award for Excellent Doctoral Student
- Ministry of Education
- National Science Foundation of China [50973037, 51173058]
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Two hypercross-linked polymer networks have been synthesized by the self-condensation of bishydroxymethyl monomer, 1,4-benzenedimethanol (BDM), and monohydroxymethyl compound, benzyl alcohol (BA). This is different from the previous reports where multifunctional monomers or cross-linkers are crucial for constructing the porous polymer networks. N-2 sorption isotherms for the polymers show that both materials are predominantly microporous with Brunauer-Emmett-Teller (BET) surface areas of 847 m(2) g(-1) for HCP-BDM and 742 m(2) g(-1) for HCP-BA. A network based on BA can also store a significant amount of CO2 (8.46 wt%) and H-2 (0.97 wt%) at 1.0 bar, and at 273 K and 77 K respectively, despite its relatively modest surface area. Based on these results, this study opens up the possibility of synthesizing porous materials using monofunctional monomers.
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