4.7 Article

The importance of ligand reactions in Cu(0)-mediated living radical polymerisation of acrylates

Journal

POLYMER CHEMISTRY
Volume 4, Issue 9, Pages 2672-2675

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py00270e

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Funding

  1. Advantage West Midlands (AWM) Science City Initiative
  2. ERDF
  3. Lubrizol
  4. Syngenta

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Ligand mediated termination events occur during the homo-polymerisation of methyl (MA) and butyl (BA) acrylate under SET-LRP (Cu(0) mediated) conditions. Careful optimization of [initiator]/[ligand] (Me(6)Tren) ratios is required to reduce termination in order to achieve optimum polymerisation.

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