Journal
POLYMER CHEMISTRY
Volume 4, Issue 13, Pages 3859-3865Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py00438d
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Funding
- Strategic Environmental Research and Development Program
- Office of Naval Research
- Air Force Office of Scientific Research, in part through the National Research Council's Research Associateship Program
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The tricyanate esters of the natural product resveratrol (1) and dihydroresveratrol (2) were synthesized and subjected to thermal curing which gave polycyanurate network polymers which exhibited glass transition temperatures of >340 degrees C and 334 degrees C, respectively. Thermal decomposition temperatures of 412 degrees C and 403 degrees C for polycyanurates of 1 and 2, respectively, were typical of this class. However, char yields (600 degrees C) of 71% and 66% for 1 and 2, respectively, were more than double that from the polycyanurate of bisphenol A dicyanate (25%).
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