4.7 Article

Enhanced stereocomplex formation of enantiomeric polylactides grafted on a polyrotaxane platform

Journal

POLYMER CHEMISTRY
Volume 4, Issue 6, Pages 1769-1773

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3py21055c

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Funding

  1. Japan Society for the Promotion of Science (JSPS)
  2. MEXT Japan, and Strategic project to Support the Formation of Research Bases at Private Universities: Matching Fund Subsidy from MEXT Japan
  3. Grants-in-Aid for Scientific Research [22300172, 24700487] Funding Source: KAKEN

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We report (i) synthesis of novel graft copolymers of a alpha-CD/PEG polyrotaxane (PRX) backbone and enantiomeric PLA side chains, PRX-g-PLLA and PRX-g-PDLA, (ii) selective stereocomplex formation on a movable PRX in the bulk state, and (iii) preparation of soft materials with continuous anisotropic phases by blending of the L- and D-isomers.

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