Journal
POLYMER CHEMISTRY
Volume 3, Issue 8, Pages 2034-2038Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2py20136d
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Funding
- Engineering and Physical Sciences Research Council
- E.ON through the E.ON-EPSRC strategic call on CCS [EP/G061785/1]
- Mahidol University
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Microporous organic polymers have been synthesised from aniline using Friedel-Crafts alkylation. Networks synthesised solely from aniline were non-porous to nitrogen. However, co-polymerisation with benzene resulted in networks with apparent Brunauaer-Emmett-Teller (BET) surface areas up to 1100 m(2) g(-1). Increased aniline content in the hyper-crosslinked networks led to improved CO2/N-2 selectivity, suggesting a strategy for the design of materials for post-combustion carbon capture.
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