Journal
POLYMER CHEMISTRY
Volume 3, Issue 10, Pages 2731-2734Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2py20283b
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Funding
- National Nature Science Foundation of China [21174094, 20904036]
- Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions
- Nature Science Key Basic Research of Jiangsu Province for Higher Education [12KJA150007]
- Program of Innovative Research Team of Soochow University
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This communication describes the first example of hydrogen bonding facilitating the control of the polymerization of 4-vinylpyridine (4VP). Well-controlled P4VP has been successfully achieved via zero-valent copper mediated radical polymerization without any additional ligand by utilizing a fluoroalcohol, HFIP, as a solvent, which can strongly interact with 4VP by hydrogen bonding.
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