Journal
POLYMER CHEMISTRY
Volume 3, Issue 4, Pages 868-870Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2py00511e
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Funding
- NRF [2010-0017552]
- Ministry of Education, Science and Technology
- Ministry of Knowledge Economy, Republic of Korea
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Adamantane-based microporous polymers were prepared by Friedel-Crafts reaction of 1-bromoadamantane with benzene, biphenyl and terphenyl and then post-functionalized with 4-nitrobenzoyl chloride. At 298 K, the CO2 uptake capacity of the functionalized polymers was increased by 18-25%, owing to the interaction between the nitro group and CO2.
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