4.7 Article

Novel electrochemical and pH stimulus-responsive supramolecular polymer with disparate pseudorotaxanes as relevant unimers

Journal

POLYMER CHEMISTRY
Volume 2, Issue 5, Pages 1068-1070

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0py00419g

Keywords

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Funding

  1. National Basic Research 973 Program [2011CB808400]
  2. NSFC/China [20972053, 20802019]
  3. Fundamental Research Funds for Central Universities [WJ0911001]
  4. Ph.D. Programs Foundation of Ministry of Education of China [200802511029]
  5. Shanghai Municipal Education Commission
  6. Shanghai Education Development Foundation

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The assembly/disassembly process of a reversible supramolecular polymer, based on homoditopic calixarene and a viologen dication connector decorated with dimethylamino portion and fluorophore, can be reversibly controlled electrochemically and by protonation/deprotonation with two disparate pseudo[2]rotaxanes worked as unimers.

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