4.7 Article

Sequential double click reactions: a highly efficient post-functionalization method for optoelectronic polymers

Journal

POLYMER CHEMISTRY
Volume 1, Issue 1, Pages 72-74

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b9py00238c

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Funding

  1. Promoting Science and Technology from MEXT, Japan

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A new post-functionalization method based on the Huisgen's 1,3-dipolar cycloaddition between azides and alkynes, followed by the atom-economic addition reaction between electron-rich alkynes and tetracyanoethylene (TCNE) was developed to introduce the donor-acceptor chromophores into polystyrene derivatives in remarkably high yields.

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