Journal
POLYMER CHEMISTRY
Volume 1, Issue 9, Pages 1437-1440Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0py00245c
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Funding
- Australian Research Council
- Russian Foundation for Basic Research [08-03-00269]
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Spin traps have been used to obtain the first direct experimental determination of the addition (5 x 10(6) L mol(-1) s(-1)), fragmentation (8 x 10(-3) s(-1)) and self-termination (6.5 x 10(2) L mol(-1) s(-1)) rate coefficients in RAFT polymerization using the interaction of a tert-butyl radical with tert-butyl dithiobenzoate at ambient temperature as a model reaction.
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