Journal
POLYMER CHEMISTRY
Volume 1, Issue 5, Pages 631-633Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0py00060d
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Funding
- Robert A. Welch Foundation (DEB) [A-0639]
- National Science Foundation [DMR-0907233, CHE-0755207]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0755207] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [0907233] Funding Source: National Science Foundation
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Smart acrylamide copolymers containing N-isopropyl and 4-N-amino-2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl (TEMPO) groups undergo reversible redox behavior leading to LCST changes. Oxidation (NaOCl/H2O) or reduction (ascorbic acid) changes the copolymer's LCST from 18 degrees C to 35-40 degrees C.
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