Journal
POLYMER CHEMISTRY
Volume 1, Issue 7, Pages 1009-1012Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0py00015a
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Funding
- Australian Research Council (ARC Centre of Excellence) [CE0561607, LE0775684, LE0668517]
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Exchange reactions between the isoindoline profluorescent nitroxide 1,1,3,3-tetramethyldibenzo[e,g]isoindolin-2-yloxyl (TMDBIO) and a TEMPO capped polystyrene were carried out. HMI conversions to the desired products were achieved using only stoichiometric ratios of nitroxide relative to polymer. The scope of this study was expanded by exploiting a di-nitroxide 9,10-bis(5-[1,1,3,3-tetramethylisoindolin-2-yloxy])anthracene (BTMIOA) as a connector between two polymer chains forming PS-nitroxide-PS systems.
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