Journal
POLYMER CHEMISTRY
Volume 1, Issue 6, Pages 837-840Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0py00066c
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Funding
- Fonds National pour la Recherche Scientifique (F.R.S.-FNRS)
- Region Wallonne
- FEDER
- University of Provence
- CNRS
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Controlled dispersion nitroxide mediated polymerization (NMP) of methyl methacrylate (MMA) was successfully carried out in supercritical carbon dioxide (scCO(2)) in the presence of a CO2-philic perfluorinated stabilizer generated in situ. This is an efficient green approach for preparing free flowing PMMA powder consisting of small sized microspheres.
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