Journal
POLYMER BULLETIN
Volume 67, Issue 2, Pages 217-226Publisher
SPRINGER
DOI: 10.1007/s00289-010-0369-8
Keywords
Semicontinuous heterophase polymerization; Mesoporous polystyrene nanoparticles; Radical polymerization
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Funding
- National Council of Science and Technology (CONACyT) [SEP 2007-84009, CB-2007-82437]
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The synthesis by semicontinuous heterophase polymerization and the characterization of mesoporous crosslinked polystyrene particles in the nanometer range (ca. 30 nm) are reported here. The particles have pores between 6 and 8 nm in diameter and pore volume around 0.40 cm(3)/g. In spite that the polymerization was not carried out at highly monomer-starved conditions, particles with narrow size distribution were obtained, which is ascribed to inter-particle hetero-coagulation at latter stages of polymerization, due to lack of enough surfactant to cover all the particles even before 45% global conversion.
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