Journal
POLYMER BULLETIN
Volume 65, Issue 5, Pages 455-463Publisher
SPRINGER
DOI: 10.1007/s00289-009-0221-1
Keywords
Dendritic star polymers; Double click reactions; One-pot synthesis
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Funding
- Special Foundation for Young Scientists of Fujian Province, China [2008F3067]
- Scientific Research Starting Foundation of Huaqiao University, China [08BS301]
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A class of well-defined dendritic star polymers with poly (epsilon-caprolactone) (PCLs) on the periphery has been prepared via one-pot double click reactions (Cu-catalyzed azide/alkyne click chemistry, i.e., CuAAC and Diels-Alder [4+2] cycloaddition reactions). The predecessors for Diels-Alder reaction, maleimide end-functionalized PCLs were produced by ring-opening polymerization (ROP). Obtained dendritic star polymers were characterized by H-1 NMR, size exclusion chromatography (SEC), UV/vis, and fluorescence spectroscopy.
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