Journal
POLYMER
Volume 54, Issue 2, Pages 596-600Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2012.12.015
Keywords
CO2 adsorption; Gas selectivity; Microporous polymer
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Funding
- Singapore National Research Foundation [NRF2009NRF-RF001-015]
- Singapore National Research Foundation CREATE program - Singapore Peking University Research Centre for a Sustainable Low-Carbon Future
- Nanyang Technological University
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Microporous polymelamine network was prepared through one-pot catalyst-free polymerization using the Schiff base reaction. Gas adsorption experiments indicate that the network possesses high CO2 uptake capacity, reaching 89.0 cm(3) g(-1) (17.9 wt%) at 1.0 bar and 273 K, along with high selectivity towards CO2 over N-2 and CH4. The porous polymeric network presents a promising potential as efficient adsorbents in clean energy applications. (C) 2012 Elsevier Ltd. All rights reserved.
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