Journal
POLYMER
Volume 51, Issue 24, Pages 5649-5662Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2010.08.067
Keywords
Proton binding; Weak polyelectrolytes; Conformation
Categories
Funding
- University of Geneva Technical University of Delft Swiss National Science Foundation
- COST Action [D43]
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This article reviews our understanding of ionization processes of weak polyelectrolytes The emphasis is put on a general introduction to site binding models which are able to account for many experimental features of linear and branched polyelectrolytes including dendrimers These models are fully compatible with the classical description of acid-base equilibria The review further discusses the nature of the site-site interaction and role of conformational equilibria Experimental charging data of numerous weak polyelectrolytes are discussed in terms of these models in detail (C) 2010 Elsevier Ltd All rights reserved
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