Journal
POLYMER
Volume 50, Issue 25, Pages 5892-5900Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2009.10.042
Keywords
Miniemulsion polymerization; Alkyds/acrylics; Post-polymerization
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Funding
- European Union [NMP3-CT-2005-011844]
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The limiting conversion commonly attained in the synthesis of waterborne alkyd/acrylic hybrid latexes hinders their industrialization. In this work, the mechanisms causing the limiting conversion were studied and post-polymerization conditions to efficiently remove the residual monomer determined. Further, it was observed that both the polymer architecture and the particle morphology were modified during post-polymerization. The mechanisms involved in the modification were investigated. (C) 2009 Elsevier Ltd. All rights reserved.
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