Journal
POLYHEDRON
Volume 31, Issue 1, Pages 265-271Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2011.09.011
Keywords
Schiff base; Vanadium(IV) complex; Non classical hydrogen bond; Epoxidation
Categories
Ask authors/readers for more resources
The Schiff base ligand N-salicylidin-2-bromoethylimine (L) and its vanadium(IV) complex, VOL2 (1), were synthesized and characterized by using X-ray, CHN, H-1 NMR and FT-IR methods. X-ray analysis shows the Schiff base ligand L acts as a bidentate (O, N) chelating ligand and coordinates via imine nitrogen and phenolato oxygen atoms to the V(IV) center. The coordination geometry around the V(IV) center in 1 is approximately square pyramidal, as indicated by the unequal metal-ligand bond distances and angles, with the basal plane formed by the N2O2 donors of the two bidentate Schiff base ligands, the two phenolato O atoms and the two imine N atoms are in the trans position. The coordination sphere of the V(IV) is completed by one oxygen atom in apical position. In the Schiff base ligand, L, there are some classical intramolecular O1-H1 center dot center dot center dot N1 and non-classical intermolecular C9-H9b center dot center dot center dot O1 hydrogen bonds, while in 1, there are two non-classical intermolecular C7-H7 center dot center dot center dot O3 and C8-H8b center dot center dot center dot O3 hydrogen bonds. The catalytic activity of 1 in epoxidation of cyclooctene was investigated in different conditions to obtain optimum conditions. The effects of solvent, oxidant, catalyst concentration and alkene/oxidant ratio were studied and the results showed that in CCl4 in the presence of tert-butylhydroperoxide in 1:3 alkene/oxidant ratio, high epoxide yield was obtained. The epoxidation of alkenes was also carried out in optimized conditions that high catalytic activity and selectivity were obtained. (C) 2011 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available