Journal
POLYHEDRON
Volume 32, Issue 1, Pages 1-9Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2011.07.015
Keywords
Uranium; Carbon dioxide; Activation; Functionalization; Small molecule
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Funding
- Deutsche Forschungsgemeinschaft (Collaborative Research Center) [SFB 583]
- Bundesministerium fur Bildung und Forschung (BMBF) [2020+]
- Bavarian California Technology Center (BaCaTeC)
- Alexander-von-Humboldt foundation
- Berkeley Actinide Post-Doctoral Fellowship
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The importance of CO2 activation and functionalization is undeniable, given the surge of effort in this area in the last few decades. Uranium complexes have begun to emerge as excellent candidates for small molecule activation, often exemplified by their varied and unprecedented chemistry with CO2. In this review, we present accounts of carbon dioxide activation and functionalization mediated by uranium complexes in various oxidation states from low-valent (+3), mid-valent (+4), to high-valent (+5). (c) 2011 Elsevier Ltd. All rights reserved.
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