Journal
POLYHEDRON
Volume 38, Issue 1, Pages 7-14Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2012.02.018
Keywords
Ortho-diferrocenylbenzene derivatives; Carbonyl cobalt; Electronic interaction
Categories
Funding
- Program for New Century Excellent Talents in University [NCET-08-858]
- Natural Science Foundation of China (NSFC) [21062011]
- Natural Science Foundation of the Inner Mongolia [20080404MS020]
Ask authors/readers for more resources
Five new ortho-diferrocenylbenzene derivatives, 1,2-diferrocenyl-4,5-dimethylbenzene (2), 1,2-diferrocenyl-4,5-diphenylbenzene (3), 1,2-diferrocenyl-4,5-ditrimethylsilylbenzene (4), 1,2-diferrocenyl-3,4,5,6-tetramethylbenzene(5), and 1,2-diferrocenyl-3,4,5,6-tetraphenyl -benzene (6), were synthesized through the cycloaddition reactions of alkynes with the cobalt cluster Co-2(CO)(6)(mu(2)-alkyne) as reaction precursors, and characterized by elemental analysis, FT-IR, NMR, and MS. The molecular structures of compounds (2-6) were identified using single-crystal X-ray diffraction, and the electron interactions between two ferrocenyl units of each of the five compounds were investigated using cyclic voltammetric techniques. The results of electrochemical experiment indicated that the charge density of the aryl bridge is the key factor that influences electron communications between two ferrocenyl units. (C) 2012 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available