4.5 Article

4-Diphenylphosphinosydnone imines as bidentate ligands

Journal

POLYHEDRON
Volume 28, Issue 12, Pages 2411-2417

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2009.04.038

Keywords

Sydnone imines; Mesoionic heterocycles; P,N-donor bidentate ligands; Palladium complexes; Crystal structure

Funding

  1. Russian Foundation for Basic Research [09-03-00603-a]
  2. International Science and Technology Center [ISTC G-1361]

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The synthesis and characterization of new 3-substituted-4-diphenylphosphinosydnone imines (1,2,3-oxadiazolium-imines-5) are reported. [GRAPHICS] These compounds react with [PdCl2(MeCN)(2)] in MeCN to afford monomeric cis-P,N-coordinated palladium complexes. (C) 2009 Elsevier Ltd. All rights reserved.

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