Journal
POLYHEDRON
Volume 28, Issue 3, Pages 562-568Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2008.11.058
Keywords
Molybdenum chelates; N, O ligands; X-ray diffraction; NMR spectroscopy
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Funding
- Ministry of Science and Technology of the Republic of Croatia [119-1101342-1082, 119-1191342-1083, 119-1193079-1084, 119-1191342-2959, 098-0982915-2944]
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The molybdenum(VI) complexes [Mo2O4(C6H4(O)CH=NCH(COO)CH2C=ONH2)(2)] (1), [MoO2-(C6H4(O)CH=NCH(COO)CH2C=(O)NH2)](3) and [MoO2(C19H19N2O5)(CH3OH)]Cl center dot CH3OH (4), of salicylaldehyde amino acid derivatives (M-asparagine or L-ornithine hydrochloride) have been synthesized and characterized. The Schiff base containing a saturated heterocyclic ring (in complex 4) is the first example Of Such a molecule derived from salicylaldehyde and the amino acid, L-ornithine hydrochloride. We proposed that the formation of a molybdenum(VI) complex coordinated by a Schiff base containing a saturated heterocyclic ring depends upon the nature of the solvent and upon the presence of molybdenum(VI). In the absence of molybdenum(VI), the condensation product obtained from the reaction of L-ornithine hydrochloride and salicylaldehyde was the Schiff base N-salicylidene-L-ornithine (5). In the dinuclear complex I and the mononuclear complexes 3 and 4, the molybdenum atoms are octahedrally coordinated with two cis oxo-oxygen atoms (in 3 and 4), oxo-bridging atoms (in 1) and the Schiff base ligand. In 3 the N-salicylidene-DL-asparaginato ligand coordinates molybdenum tetradentately while in 1 and 4 the Schiff base ligand acts as a tridentate ligand. (C) 2008 Elsevier Ltd. All rights reserved.
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