Journal
POLIMEROS-CIENCIA E TECNOLOGIA
Volume 22, Issue 2, Pages 117-124Publisher
ASSOC BRASIL POLIMEROS
DOI: 10.1590/S0104-14282012005000017
Keywords
Thermoplastic polyurethane; functionalized multi-walled carbon nanotube; spray coating; buckypaper
Categories
Funding
- Brazilian agencies CNPq (Conselho Nacional de Desenvolvimento Cientifico e Tecnologico)
- FAPEMIG (Fundacao de Amparo a Pesquisa do Estado de Minas Gerais)
- Rede Nacional de Pesquisa em Nanotubos de Carbono/MCT/Brazil
- Petrobras
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Multi-walled carbon nanotubes (MWCNTs) functionalized with amine and carboxyl groups were used to prepare polyurethane/ MWCNT nanocomposites in two distinct concentrations: a lower value of 1 mass% (spray coating) and a higher one of similar to 50 mass% (buckypaper based). The MWCNT-NH2 sample contained only 0.5 mass% of amine groups, whereas MWCNT-COOH contained 5 mass% of carboxyl groups. The MWCNT functionalized with low amine group content showed improved thermal properties when compared to neat thermoplastic polyurethane (TPU) and MWCNT-COOH based nanocomposites. The electrical conductivity of the polyurethane elastomer was greatly increased from 10(-12) to similar to 10(-5) S cm(-1) in the 1 mass% nanotube composite and to 7 S cm(-1) for the MWCNT-NH2 buckypaper-based nanocomposite. Furthermore, the relative high content of functional groups in the MWCNT-COOH sample, which disrupt the sp(2) structure in the nanotube walls, led to inferior properties; for instance the conductivity of the buckypaper based composite is one order of magnitude lower when using MWCNT-COOH in comparison with the MWCNT-NH2. These results show the range of property design possibilities available with the elastomeric polyurethane nanocomposite by tailoring the functional group content and the carbon nanotube load.
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