4.0 Article

Preparation of Modified Clay with Cetylpyridinium Chloride and Evaluation of Their Interaction with PVC

Journal

POLIMEROS-CIENCIA E TECNOLOGIA
Volume 20, Issue 3, Pages 231-235

Publisher

ASSOC BRASIL POLIMEROS
DOI: 10.1590/S0104-14282010005000031

Keywords

Montmorillonite; PVC; XRD; low field NMR

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A modified silicate with cetylpyridinium was prepared from sodium clay with cation exchange in solution. The amount of modification agent for clay and the reaction time were evaluated. The materials produced were characterized using X ray diffraction (XRD), termogravimetric analysis (TGA) and low field nuclear magnetic resonance (NMR). The formation of new organic clay was confirmed, which was introduced in PVC for the formation of nanocomposites. The beginning of degradation of the new clay occurred at temperatures higher than commonly used in the processing of PVC. The nanocomposites were partially exfoliated and partially intercalated.

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