4.8 Article

Bimetallic lanthanide complexes that display a ratiometric response to oxygen concentrations

Journal

CHEMICAL SCIENCE
Volume 6, Issue 3, Pages 2054-2059

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4sc03827d

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Funding

  1. University of Oxford
  2. University of Durham
  3. Danish Council for Independent Research
  4. Carlsberg Foundation
  5. Cancer Research UK [16466] Funding Source: researchfish

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A pair of hetero-bimetallic lanthanide complexes containing terbium and europium ions have been prepared by coupling kinetically stable complexes together using an Ugi methodology to incorporate a naphthyl chromophore. Both complexes exhibit emission from terbium and europium in solution. The terbium centred emission varies with dissolved oxygen concentration, while the europium intensity remains essentially constant in one of the complexes.

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