Journal
CHEMICAL SCIENCE
Volume 6, Issue 5, Pages 2903-2908Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc00295h
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Funding
- Spanish MINECO [SAF2013-41943-R, SAF2010-20822-C02]
- ERDF
- European Research Council [340055]
- Xunta de Galicia [GRC2013-041]
- Fundacao para a Ciencia e Tecnologia (Portugal)
- POPH/FSE [SFRH/BD/60214/2009]
- Fundação para a Ciência e a Tecnologia [SFRH/BD/60214/2009] Funding Source: FCT
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Allenamides participate as two-carbon components in an intermolecular [2 + 2 + 2] cycloaddition with alkenes and aldehydes when treated with catalytic amounts of a phosphite gold complex. The reaction is highly regio-and chemoselective, and works with different types of alkenes, including styrenes, enol ethers or enamides, as well as with aromatic and aliphatic aldehydes. Accordingly, different types of 2,6-disubstituted tetrahydropyrans can be stereoselectively assembled in a single step from commercial or very accessible starting materials.
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