Journal
CHEMICAL SCIENCE
Volume 6, Issue 5, Pages 2928-2931Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc00248f
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Funding
- National Natural Science Foundation of China
- National Basic Research Program of China [2012CB821600]
- 111 project of the Ministry of Education of China [B06005]
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A new iridium catalyst containing an imine-diphosphine ligand has been developed, which showed high efficiency for the hydrogenation of CO2 to formate (yield up to 99%, TON up to 450 000). A possible catalytic mechanism is proposed, in which the imine group of the catalyst plays a key role in the cleavage of H-2 and the activation of CO2.
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