Journal
CHEMICAL SCIENCE
Volume 6, Issue 5, Pages 3087-3094Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc00790a
Keywords
-
Categories
Funding
- MICINN [CTQ 2008-05827/BQU, CTQ 2009-12216/BQU]
- Fundacion Seneca-CARM [08661/PI/08]
- Marie Curie COFUND program [267143]
- Marie Curie U-IMPACT program [267143]
- University of Glasgow
- EPSRC
Ask authors/readers for more resources
A cyclic network of chemical reactions has been conceived for exchanging the dynamic behaviour of di(acylamino)pyridine-based rotaxanes and surrogates. X-ray diffraction studies revealed the intercomponent interactions in these interlocked compounds and were consistent with those found in solution by dynamic NMR experiments. This particular binding site was incorporated into a molecular shuttle enabled for accessing two states with an outstanding positional discrimination through chemical manipulation. Furthermore, the ability of the di(acylamino) pyridine domain to associate with external binders with a complementary array of HB donor and acceptor sites was exploited for the advance of an unprecedented electrochemical switch operating through a reversible anion radical recognition process.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available