Journal
CHEMICAL SCIENCE
Volume 6, Issue 11, Pages 6367-6372Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc02336j
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Funding
- NSERC of Canada
- Canada Research Chair
- Alexander von Humboldt Foundation
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The cationic N-3-species [(p-HC6F4)(3)PN3](+) (1) featuring a perfluoro-arene phosphonium group serves as a N-3(+)-source in stoichiometric reactions with several Lewis bases (L) allowing for the stepwise formation of [(L)N-3](+) and [(L)(2)N-3](+) cations (L = phosphine, carbene) with liberation of (p-HC6F4)(3)P. X-Ray diffraction analysis and computational studies provide insight into the bonding in these remarkably stable azidocations.
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