Journal
CHEMICAL SCIENCE
Volume 6, Issue 11, Pages 6325-6333Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc02024g
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Funding
- Gobierno de Espana MINECO [CTQ2011-23014, CTQ2014-56295-R, SEV-2013-0319]
- ICIQ Foundation
- MINECO
- ICREA Funding Source: Custom
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In this work, we describe the stoichiometrically controlled self-assembly process of tetraurea calix[4]pyrrole 1 with a polar neutral guest, trimethylamine N-oxide or beta-alanine betaine, and methyltrioctylammonium chloride (MTOACl) salt into two supramolecular architectures which differ in morphology and stoichiometry. Whereas an equimolar solution of tetraurea calixpyrrole 1, polar guest and MTOACl produces a four-particle inclusion assembly, a mixture of the same components in a 2 : 1 : 1 molar ratio induces the formation of a dimeric capsular assembly displaying multiple guests which are orderly co-encapsulated. The influence of other polar guests and ammonium salts on the self-assembly process is also described.
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