Journal
CHEMICAL SCIENCE
Volume 6, Issue 6, Pages 3373-3377Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5sc00720h
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Funding
- University of Michigan Department of Chemistry
- NSF-GRFP
- UM Rackham Graduate School
- NSF [CHE-0840456]
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Nitrite reduction by a copper complex featuring a proton-responsive tripodal ligand is demonstrated. Gaseous nitric oxide was confirmed as the sole NOX by-product in quantitative yield. DFT calculations predict that nitrite reduction occurs via a proton and electron transfer process mediated by the ligand. The reported mechanism parallels nitrite reduction by copper nitrite reductase.
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