4.5 Article

A Study of Sulfonol Decomposition in Water Solutions Under the Action of Dielectric Barrier Discharge in the Presence of Different Heterogeneous Catalysts

Journal

PLASMA CHEMISTRY AND PLASMA PROCESSING
Volume 32, Issue 1, Pages 97-107

Publisher

SPRINGER
DOI: 10.1007/s11090-011-9326-z

Keywords

Oxygen surface barrier discharge; Surfactant; Phenol; Decomposition; Catalysts

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The decomposition kinetics of sulfonol (surfactant) in water solutions as well as the formation kinetics of decomposition products under the action of an oxygen dielectric barrier discharge (DBD) at atmospheric pressure in the presence or absence of TiO2, NiO and Ag2O catalysts in the plasma zone was studied. The DBD discharge was shown to have high decomposition efficiency (phenol-up to 98%, sulfonol-up to 80%). In a plasma-catalytic hybrid process, the efficiency of organic substances decomposition was higher than efficiency for the DBD treatment without catalyst. The catalysts application resulted in a change in the ratio and yield of decomposition products.

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