Journal
PHYSICS-USPEKHI
Volume 52, Issue 8, Pages 789-810Publisher
TURPION LTD
DOI: 10.3367/UFNe.0179.200908b.0837
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Funding
- RFBR [09-02-00171-a, 07-02-00226, 09-02-00127]
- Federal Agency of Science and Innovation [MK-4278.2008.2]
- Presidium of the Russian Academy of Sciences [5, 7]
- Leading Science Schools of the Ministry of Education and Science of the Russian Federation [2.1.1/3199]
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Complex cobalt oxides known as cobaltites are reviewed, including LnCoO(3)-based perovskite-structured rare-earth cobaltites (where Ln is lanthanum or a lanthanide), quasi-two-dimensional and quasi-one-dimensional cobaltites of the types LnCo(2)O(5+delta), La2CoO4, and Ca3Co2O8, and NaxCoO2 center dot yH(2)O superconducting compounds. Key experimental and theoretical results are presented, with emphasis on the interplay between charge, spin, and orbital degrees of freedom. Two problems of specific relevance to cobaltites - the spin state instability of Co3+ ions in LnCoO(3), and the nature of superconductivity in NaxCoO2 center dot yH(2)O - are also given significant attention.
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