4.2 Article

Novel sensible thermal storage material from natural minerals

Journal

PHYSICS AND CHEMISTRY OF MINERALS
Volume 40, Issue 9, Pages 681-689

Publisher

SPRINGER
DOI: 10.1007/s00269-013-0603-7

Keywords

Sensible thermal storage material; Clay minerals; Thermal conductivity; Structural evolution

Funding

  1. National Science Fund for Distinguished Young Scholars [51225403]
  2. Specialized Research Fund for the Doctoral Program of Higher Education [20120162110079]
  3. Scientific Research Foundation for ROCS of SEM [2011-1139]

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Novel sensible thermal storage materials (TSM) were first synthesized via thermally treating the green compact obtained using clay, kaolin tailings, and hematite as major raw materials. The samples were characterized using differential scanning calorimetry and thermogravimetric, X-ray diffraction, thermal conductivities, petrography analysis, Fourier transformation infrared spectroscopy, and scanning electron microscopy. The thermal conductivity of the green compact reached 1.11-1.64 W m(-1) K-1 after thermally treated at 200-1,000 A degrees C. The clay component was proven to have a predominant effect on the thermal conductivity of the green compact. Kaolin tailings could act as a modulator for adjusting the thermal conductivity from 1.42 to 1.92 W m(-1) K-1. Affecting mechanism of microstructural change of main components during sintering on thermal conductivity of TSM was prominently investigated. TSM could provide a potential candidate for thermal energy storage systems of concentrated solar power.

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