Efficient Atomic-Scale Kinetics through a Complex Heterophase Interface

Atomic-scale imaging and first-principles modeling are applied to the heterophase interface between the Al-Cu solid solution (alpha(Cu)) and theta' (Al2Cu) phases. Contrary to recent studies, our observations reveal a diffuse interface of complex but well-defined structure that enables the progression from alpha(Cu) to theta' over a distance of approximate to 1 nm. We demonstrate that, surprisingly, the observed interfacial structure is not preferred on energetic grounds. Rather, the excess in interfacial energy is compensated by efficient atomic-scale kinetics of the alpha(Cu) -> theta' phase transformation.