Evidence for Short-Range-Ordered Charge Stripes Far above the Charge-Ordering Transition in La1.67Sr0.33NiO4

The temperature evolution of structural effects associated with charge order (CO) and spin order in La1.67Sr0.33NiO4 has been investigated using neutron powder diffraction. We report an anomalous shrinking of the c / a lattice parameter ratio that correlates with T-CO. The sign of this change can be explained by the change in interlayer Coulomb energy between the static-stripe-ordered state and the fluctuating-stripe-ordered state or the charge-disordered state. In addition, we identify a contribution to the mean-square displacements of Ni and in-plane O atoms whose width correlates quite well with the size of the pseudogap extracted from the reported optical conductivity, with a non-Debye-like component that persists below and well above T-CO. We infer that dynamic charge-stripe correlations survive to T similar to 2T(CO).