Journal
PHYSICAL REVIEW LETTERS
Volume 106, Issue 18, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.106.187403
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Funding
- Marsden Fund [MAU0606]
- Education NZ
- MacDiarmid Institute
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First-principles calculations show that the optical UV absorption onset of solid water is blueshifted with increasing pressure. Across several crystal structures and a wide pressure range, the optical gap increases almost linearly with external pressure, making solid water more transparent. The origin of this unusual effect can be traced back to an increased Stark shift caused by water's electrostatic environment at smaller volumes.
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