Journal
PHYSICAL REVIEW LETTERS
Volume 107, Issue 21, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.107.216801
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Funding
- Agence Nationale de la Recherche [ANR-07-BLAN-0139]
- International Center for Frontier Research in Chemistry (FRC)
- Agence Nationale de la Recherche (ANR) [ANR-07-BLAN-0139] Funding Source: Agence Nationale de la Recherche (ANR)
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Low-temperature scanning tunneling microscopy and spectroscopy combined with first-principles simulations reveal a nondissociative physisorption of ferrocene molecules on a Cu(111) surface, giving rise to ordered molecular layers. At the interface, a 2D-like electronic band is found, which shows an identical dispersion as the Cu(111) Shockley surface-state band. Subsequent deposition of Cu atoms forms charged organometallic compounds that localize interface-state electrons.
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