4.8 Article

Hydrodynamics of Liquids of Chiral Molecules and Suspensions Containing Chiral Particles

Journal

PHYSICAL REVIEW LETTERS
Volume 104, Issue 19, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.104.198301

Keywords

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Funding

  1. DOE [DE-FG020-7ER46452, DE-FG02-00ER41132]
  2. NSF [DMR-0704151]

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We obtain hydrodynamic equations describing a fluid consisting of chiral molecules or a suspension of chiral particles in a Newtonian fluid. The hydrodynamic velocity and stresses arising in a flowing chiral liquid have components that are forbidden by symmetry in a Newtonian liquid. For example, a chiral liquid in a Poiseuille flow between parallel plates exerts forces on the plates, which are perpendicular to the flow. A generic flow results in spatial separation of particles of different chirality. Thus even a racemic suspension will exhibit chiral properties in a generic flow. A suspension of particles of random shape in a Newtonian liquid is described by equations which are similar to those describing a racemic mixture of chiral particles in a liquid.

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