Journal
PHYSICAL REVIEW LETTERS
Volume 102, Issue 14, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.102.145901
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- EC [FP6NEST]
- OTKA [NK60984]
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We report on the extraordinary superionic conductivity in the fulleride polymer Li4C60, a crystalline material with no disorder. Li-7, NMR, and dc frequency dependent conductivity show uncorrelated ionic hopping across small energy barriers (Delta E-a similar to 200 meV) and an ionic conductivity of 10(-2) S/cm at room temperature, higher than in standard ionic conductors. Ab initio calculations of the molecular structure find intrinsic unoccupied interstitial sites that can be filled by Li+ cations in stoichiometric Li4C60 even at low temperatures. The low energy required for the occupation of these sites allows a sizable Li+ diffusion above 130 K. The results suggest novel application of lithium intercalated fullerides as electrodes in Li ions batteries.
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