4.8 Article

Hund's Paradox and the Collisional Stabilization of Chiral Molecules

Journal

PHYSICAL REVIEW LETTERS
Volume 103, Issue 2, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.103.023202

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Funding

  1. DFG

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We identify the dominant collisional decoherence mechanism which serves to stabilize and superselect the configuration states of chiral molecules. A high-energy description of this effect is compared to the results of the exact molecular scattering problem, obtained by solving the coupled-channel equations. It allows us to predict the experimental conditions for observing the collisional suppression of the tunneling dynamics between the left- and the right-handed configuration of D(2)S(2) molecules.

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