Vanishing Quantum Discord is Necessary and Sufficient for Completely Positive Maps

Two long-standing open problems in quantum theory are to characterize the class of initial system-bath states for which quantum dynamics is equivalent to (i) a map between the initial and final system states, and (ii) a completely positive (CP) map. The CP map problem is especially important, due to the widespread use of such maps in quantum information processing and open quantum systems theory. Here we settle both these questions by showing that the answer to the first is all, with the resulting map being Hermitian, and that the answer to the second is that CP maps arise exclusively from the class of separable states with vanishing quantum discord.