4.8 Article

Photoinduced Separation of Chiral Isomers in a Classical Buffer Gas

Journal

PHYSICAL REVIEW LETTERS
Volume 102, Issue 6, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.102.063004

Keywords

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Funding

  1. NSF [DMR-0704151]
  2. DOE [DE-FG02-07ER46452]

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We develop a theory of photoinduced drift of chiral molecules or small particles in classical buffer gases. In the absence of a magnetic field there exists a flux of chiral molecules, provided the electromagnetic field is circularly polarized. It has opposite signs for different chiral isomers. In the presence of a magnetic field the flux can be also induced by a linearly polarized (or unpolarized) electromagnetic field. The magnitude of the flux is not proportional to either linear or orbital momentum of the electromagnetic field.

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