Journal
PHYSICAL REVIEW E
Volume 89, Issue 3, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevE.89.032302
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Funding
- Israel Science Foundation [184/12]
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The response of an electrolyte solution bounded between two blocking electrodes subjected to an ac voltage is considered. We focus on the pertinent thin-double-layer limit, where this response is governed by a reduced dynamic model [L. Hojgaard Olesen, M. Z. Bazant, and H. Bruus, Phys. Rev. E 82, 011501 (2010)]. During a transient stage, the system is nonlinearly entrained towards periodic oscillations of the same frequency as that of the applied voltage. Employing a strained-coordinate perturbation scheme, valid for moderately large values of the applied voltage amplitude V, we obtain a closed-form asymptotic approximation for the periodic orbit which is in remarkable agreement with numerical computations. The analysis elucidates the nonlinear characteristics of the system, including a slow (logarithmic) growth of the zeta-potential amplitude with V and a phase straining scaling as V-1 ln V. In addition, an asymptotic current-voltage relation is provided, capturing the numerically observed rapid temporal variations in the electric current.
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